How would you get this effect?

how about just using gradient and multiplying / darkening out the dark areas? just an idea.

and - don't know about the colors, sorry ;)
 
It's cross processed ;)

Originally a film developing process, but can now be achieved through altering the colour channels in Photoshop.

A goggle search for the term should give you some tutorials.
 
I think the photograph used 1 external flash. Then he altered the colour channels.
 

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