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I used a reflector when taking the shot just to get some light into the eyes. A lot of the tonal range is from the camera which had a high dynamic range (d810) which does makes a difference. I'm not familiar with gray scale conversions. Sounds interesting though.
I keep forgetting to carry my collapsible reflector, but from now on I think I'll tie it to my wrist! Surprisingly your D810 and my K3II are very close on dynamic range, though I think the D810 is less likely to pump up the reds in Caucasian skin. Are you saying you've created this look in camera rather than post?