is there a complication with using webshots based photos on this forum??? i have a webshots site and I thought I linked them correctly...but obviously not.
Your sunset picture is really nice. I can only see one sunset photo though. And it looks to me like the buildings are a little bit out of focus. Might just be my fryed eyes though coz I looked at a few of your other pics aswell and they're a little out of focus too.
The sky doesn't look PSed to me, so if it is - great job!
The only thing that bothers me here is the burnout in the bottom right part. Maybe you could take a couple of different exposure lengths and then combine them all so you get the best parts of each area of the photo.