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Moving her away from wall and using a black background would have surely also help, but...
I beg to differ. If you have the right tools and know how to use them, then flash strobe lighting can be as good of if not better a solution.
There's no way this would have worked just using the window light. It wasn't bright enough and it would have been soft from the person moving. Exposed for ambient with one strobe with an octobox in the upper right of the frame. I can give you a link to thousands of photos where you wouldn't be able to tell whether or not ambient or flash was used.
Edit: See any harsh shadows?
I've been doing a lot of the longer exposure/diffused light with a single fire of the flash to even out the light in the room. That actually works quite well as long as there is nothing moving in the shot. I've found that relying exclusively on the light from windows in MOST locations leads to "overly dramatic" lighting at best.
It's continues to amaze me how little light we need to see and yet how much is necessary to properly expose a picture.