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I would not have chosen that wardrobe for her, it's not very flattering... I agree with JackRabbit I would use a natural bg, looks like something out of Space, the TV channel. Also it looks like you used too much fill light, her face is a bit washed out.
From a posing standpoint, especially with women, try not to shoot them straight on. The human body is at its widest when you shoot it straight on. Have the model angle or twist her body. Not only does it make the body look thinner but it makes for a more pleasing shot.
gotta agree with rabbit and others.
the digital backdrops are killing the photos, as is squishing them horizontally.
what was it originally shot in front of?
Shooting at a wider aperture, like f/4 or so will help to throw the background more out of focus. Of course, if she is standing on the muslin and it is wrinkled under her feet, those wrinkles will show up, even if the background is more out of focus, so you might need to do some post production work on the muslin at her feet. What bugs me the most about the shots is that she looks "stretched", almost as if she were made of taffy and were pulled to make her taller and skinnier...