As long as you can trigger it, yes, it should work if you set it up right if it has the proper capability to do what you need. But I know little to nothing about the operation of that flash. I am referring to whether or not you can safely use that model flash with any DSLR.
There is a website that shows what flashes ARE and ARE NOT safe to use on the hot shoe of a DSLR (because of the trigger voltage).
According to that website the Canon Speedlight 199A IS CONSIDERED to be safe for use ON a DSLR, so your flash can be used either on or off-camera.
Maybe you can find operating instructions, or a review of the flash somewhere online.
Yes, it should work as a remote flash.
I don't recall the details of that flash...but I don't think that it has manual controls. Meaning that when it's not connected to a compatible camera, it will fire at full power every time. That's OK, at least it's consistent, but it's not as versatile as a flash that has manually adjustable power.
Also, some flashes may go to sleep after a set time when mounted on a remote trigger. I had a 420EZ that do that. And the only way to bring it back up is power cycle the flash.