oldhippy
Been spending a lot of time on here!
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Good call on the lens capFrom the looks of it, behind the dog is a door with a window. You used flash to front-light (can be seen in the reflections in the hair, and the catchlight in the dog's eye), and the light spilling in from the door window provided a sort of rim light. I suspect that the slightly purplish glow is actually lens flare from the door window light. If you had a lens hood you may have blocked that light from entering the lens and the flare would have been minimized.