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Wait, no. That isn't what Exposure Compensation does. At all. That's a fair description for spot metering.preventing it being biased by darker zones in the frame.
Space Face posted a correct link. EC does nothing at all to your image in full manual. Twirl the EC dial all day and get the same exposures.
I think you were trying to point out the blown whites in the original image. EC might be a solution in an auto mode like auto ISO.