Who ever the photo is for should look at it and tell you what they think...
They're for me.

I refuse to talk to myself, though.
The first one was my first attempt at doing anything like this. It's odd, though, other than sharpening, I really didn't do much to the eyes in either photo. The simple act of bumping the exposure just brought out the blue. The first one had the catch lights accentuated a bit because they were really not there.
Do you mind sharing the PS technique
Not at all.
In Camera Raw, after setting the white balance, I bumped the exposure up until it blew out the backgrounds. Then adjusted the recovery such that it brought some of her details back. I used just a touch of 'fill' because the lighting in both situations was pretty much crap. It's really about balancing those three out to get the 'look' I was looking for. I've by no means, as you can tell, perfected it.
Once I finished with camera raw, I brought it into PS and adjusted the levels get rid of the 'haze' effect, then cloned/healed out any unwanted artifacts (in the first picture, she has a green bow slightly visible in her hair which had to go, in the second, there were some stuffed animals in the background and a pillow and the 'wood tower' back there was her toy box which only went about half way up the photo to start out with). Converted to Lab color and ran a pretty aggressive sharpen on just the Lightness layer.
That's really about it. Nothing terribly fancy.