Big Mike - please don't confuse the guy with inaccurate info. Matrix would never be shot under fluorescent lights.
Do you mean like this?
http://h2racer.com/matrix/pics/8x12a.jpg
http://www.progblog.de/uploads/filme/unleashed.jpg
In a lot of the scenes in the subway fight, neither neo nor smith are actually in the shot. The're inserted later with green screen, and often lit up separately from the background.
This is the reason why they bring 5 truckloads of lighting equipment to the set. They can get it exactly the way they want it.
You don't have this option. So use strong lighting from the side and from the back. This would give your subject mystery.
Sin City was shot primarily with side lighting and backlighting.
[ame]http://images.amazon.com/images/P/B00005JNTX.01.LZZZZZZZ.jpg[/ame]
In here, they took every portrait separately and then photoshopped it together.
Bruce Willis is lit from the sides and from behind.
The stripper chick is from behind from the left and from the side on the right. The light is also diffused, to make her more feminine.
Also strong hairlight, which gives a halo around her... giving the surreal look.
Does this help?