Like, if I am using the 50mm, what circumstance would make me want to switch and put on my 85mm?
Say... if you have a person or persons in front of your camera. That would be a good time to reach for the 85mm.
Think of it this way: With you format (camera) [I'm presuming you do not have a "full frame" sensor], the NORMAL focal length is approximately 40mm. So anything shorter than that can be considered as "wide angle" and anything longer than that can be considered as "telephoto."
There are FIXED FOCAL LENGTH lenses (often times referred to as "prime" lenses), and there are variable focal length lenses which are called ZOOM lenses.
A lens is also described by it's maximum aperture. So the lens you are questioning is a FIXED FOCAL LENGTH, TELEPHOTO lens with a maximum aperture of f 1.8, which is considered to be pretty "bright" or "fast" for a lens of that length.
The brighter (or faster) the lens, the less light needed to make a proper exposure. ALSO... the wider the aperture you use, the SHALLOWER the depth of field you achieve. So, with your 85mm... shooting wide open at f 1.8, you will have very shallow depth of field.
Personally, I feel f 1.8 is not a good choice for shooting kids... or groups... or most portraits. I would choose something between f 4 and f 8, favoring the smaller end of this range.
Kids move. With a very shallow depth of field, it's likely they will move into and out of acceptable focus. And when posing groups, the subject will likely be too deep to shoot at anything brighter than f 5.6 or f 8.
I hope this helps.
-Pete