I first set an exposure based on the sky.
Say the camera wants 1/125 @ f11 @ iso 400 if spot metering on the subject's face
And 1/1000 @ f16 @ iso 400 if spot metering on the sky
I'll set my camera up in M(anual) mode for an EQUIVALENT exposure to the sky.
Say 1/250 @ f11 @ iso 100. Two stops more light via slower shutter offset by two stops slower film.
Then I'll compare that exposure to the meter reading for the face...
1/250 va 1/125 = needs one more stop of light. iso 100 vs iso 400 needs two more stops of light.
Now tell your speedlight to add +3. (alterntively, I'll put it in full power Manual mode).
Give it a try and see what you get.
If the sky isn't dark enough, I'll stop down one more, or tr a faster shuffer (if the flash will still sync at that speed).
If the subject is too dark or too light, I'll adjsut the flash (either +/- ev, or add / reduce power in manual mode). Sometimes I'll adjsut the aperture to lighten the subject, and adj the shutter to offset darken the sky keepign it the same.
ADJSUT THE SKY w/ the shutter, and the subject w/ the aperture and/or flash power.
With practice you should be able to get it to something useful in a couple minutes or less.
HINT: all the works because the flash burst lasts microseconds, so the shutter speed is (mostly) irrelevant to the foreground / subject.
This decoupling lets you adjsut foreground and background separately, even when your flash is seemingly not adjustable.