Just a suggestion. One of the primary rules in working with high contrast, such as your bright sky and your very dark barn is this: Expose for shadows develop for highlights. In other words, when I have this type of situation, which is quite common to photographers, I do one of two things; I meter for the darkest value, ie. the shadows, in your instance, and then expose the photo. (there are other things I do which is to consider, in my case, the films latitudes, or, light sensitivities from the darkest to the whitest, and stop down 1/2 stop from my meters reading, in your case, your cameras.)
You can meter for shadows with your camera if you have an exposure lock. Just take your cameras meter close to the darkest element in your composition take your reading there and then shoot away. This may ease the amount of time spent in Photoshop as you then have a nicely exposed dark and have to adjust only for the skies highlites.
Another item you should place in your camera bag, available at most photo shops, is an 18% gray card. This is what your camera is reading, 18% average of the total light value in your composition. You adjust the gray card to reflect the light that falls on your subject, expose for that reading and you have it.