My Canon DSLRs don't have the capability to do multiple exposures in-camera, but here's one from my film days that I have handy, and it should apply equally to your situation:
First, I masked off half the lens. Then I shot the frame, exposing properly, just as though I were taking a single shot. If I'd left it at that, I'd have gotten a photo that's half black (unexposed) and half a Statue of Liberty from the waist up.
Instead, I then flipped the mask to mask off the other half of the lens, reset the shutter without moving the film, flipped the camera 180 degrees, and took the second shot, exposing the side that was still all black (unexposed).
The result is as you see above.
There's a little ghosting in the middle because my mask wasn't perfect and my aperture was not as tight as it could have been.
We did the same with partial masks, where you cut out a shape from the black mask, say a circle, star, keyhole or other shape, then have a corresponding shape as the other mask, inverted. So, one mask has a hole in it to shoot through, the corresponding mask has a black dot on it so that you can shoot everything but. Through those methods, we'd double-expose to put photos of couples in champaign glasses and so on.
You could cut and mask several shapes, do several exposures, and by being very creative and very carefully masking, you could do quite a bit with them, but as I said earlier, it was a real chore, and you never knew for sure how well it was going to work back in the film days until you'd gotten it developed.