I like the idea, but by shooting this way you create an exposure problem. Effectively it is a backlit portrait. Or a poorly lit subject against a bright background. To pull this kind of portrait out you need a reflector if the sun is bright, or a flash. Alternatively shoot at sunset, positioning yourself so that the low sun lits ther faces. Otherwise your portraits will be underexposed or , if you expose for the face , your background will be overexposed and washed out We can see both here.