Predictive color temperature model

How do you account for large scale phenomena, such as the eruption of volcanoes? For years after Mt. St. Helens erupted, I remember that there were consistently dramatically different colored skies and sunsets than normal.
 
As far as I know, there aren't too many of those events in the past several years, so those effects should be minimal. I would think pollution would have a much larger and "real" effect than phenomena like volcanoes.
 

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