Well, you needed more actual "lighting" in the dark areas. The dark areas are quite under-exposed compared against the light-struck parts of her face...the shadow side of the exposure is not all that clean...on a subject like a standing woman, your light source was too small and too far behind the line of her nose, so the whole,entire left hand side of frame #1 was in shadow...to avoid loss of image quality in the final image, you need to keep that AS SHADOW, or risk showing the sensor's rendering of the darks with some chroma noise...the color speckling is not "all that bad", but it is there. The issue is that if the shadows are kept DARK, then the image looks fine; the problem arises when a severely under-exposued, dark toned area, like her hair, needs to be "lifted" in post...
If you would have moved the light around and aimed at her from a more frontal angle, then there would have been more light in the shadowed parts of her, and her dark hair would have been moved "upward" in the exposure.
The other option would have been to have exposed MORE-generously, like f/5.6, and then pulling the highlights "back". That would have been preferable to under-exposing and then "lifting" the exposure in post-processing.
You ask if this is a technical error. Well...I suppose it could be considered simply under-exposing. Or shooting with inadequate fill lighting. Or less-than-optimal placement of the main lighting. Or not having a flash meter to guide you as to the proper exposure. In a single-light shot like this, the proper placement of the main light is critical. I suspect this is a softbox; a different modifier might have bailed you out a bit more. Technical error or technique error? I dunno....just words...