Thanks for all the replies! I will fiddle with the settings in LR, I probably should invest in PS, but I keep resisting for some reason. In any case, I did notice that the water really wanted to blow out even though the overall scene was darker. I do have a few of the waterfall with a slow shutter speed shot hand-held. They came out alright, but I like trying to freeze the water. Now that I have a proper landscape lens, I might get some filters to match it.
I don't mind the blue-ish cast in the mountains much. They don't call them the Blue Ridge mountains for nothing lol. Though a little clarity might not hurt.