Yes, the fleshtones look very acceptable, very realistic to me. His hair color looks believable as well. His right eye (camera left eye), however, looks unnaturally blue when I look at the Original size on Flickr. And yes...by using a gray backdrop with a gel fired at it, one achieves a darker, more-saturated color than with a white background--all things being equal. AND, with the gray background, there is less light reflected back toward the subject, and that holds true at each and every power level. At the end of the day yesterday, I read that you were using the Alien Bee 400 + gel as the background light, and an SB 600 as the hairlight...my experience with white backgrounds is that it takes almost "no light" to get a gelled color with a 200 to 400 watt-second studio flash fired onto a white seamless, and that for gel-coloring, speedlights or very low watt-second studio flash, like 12.5 watt-seconds to 25 watt-seconds, can actually be quite enough when the background screen is white.
I took the liberty of messing around with Selective Color, to change the background color to one that would coordinate more harmoniously with his brown hair and brown sweater. If you look closely, you can see that there *is* a small amount of blowback visible around the perimeter of his head, which shows when the selective color change is applied pretty heavily, as it was here.
Selective Color> Magentas> Cyan +65 units, Magenta Minus 100 units, Yellow + 100 units, Black Minus 2 units.
Selective Color>Yellows> Cyan Minus 100 units, Magenta +97 units, Yellow Minus 37 units, Black +1. I messed with the Yellows here to make his skin just a slight bit more rosy and youthful-looking.