You don't draw or design the graphic elements of your site in dreamweaver. You put it all together with it. It's not a graphic design app.
You need something like, Illustrator, CorelDraw, Photoshop etc. If you want total control of the appearance of your website use Flash as your main app. Much easier to work with as far as building the interface, placing buttons or other things where you want. Flash doesn't need to be animated and crazy, you can build very static sites with it.
I've worked with it for years. You can use any ftp app to upload to your hosting server.