Portrait of a girl, flash and natural light.

[The Phototron]

1.

2.

3. No smoothing, just wide aperture and soft lighting.

BTW, the don't bother commenting on the eyes looking too white, it's fine on print and 100% zoom.

 

[JimmyO]

The last one looks over exposed but the color of the eyes is amazing

Not that i would be able how to tell you how to do it but if you could remove some of the blemishes on PS that would help.