In terms of spots where it should be dark, if you want it to be black, I'd just PP black over the photo. Generally I do this by filling a new layer in black, then using a layer mask to mask-in the black. Feels more intuitive to me and affords more control.
If it's a part of the image with detail you want to keep, but darken, I generally use an exposure adjustment layer and layer mask with that. Alternately, a brightness/contrast adjustment layer can work, or for those without CS4, copy the image, paste in a new layer, adjust the brightness of that layer, mask it all out, and then mask-in the parts you want darker.
As for WB, this looks a wee warm to my taste, but that's just to my taste. Key when dealing with city lights is to add magenta tint much of the time, so as to lessen those fugly fluorescents and move them closer to white (this is especially useful with cityscapes at night; few people mind a magenta-ish sky, but most people will think "yuck" when they see sodium-vapour-like, puke green lights).
The easiest solution is to shoot RAW, and adjust it all in post to suit your taste.