The Canon 6D does not have a built-in radio trigger. I may either use one of the 600 as an IR trigger for what I have or take your advice and rent an ST-E3-RT or even another 600. Do you think the lighting would be too uneven by using one of the 600 on my camera (or on a bracket) and the other on a stand? If that would be too uneven, is the best flash position just to have one on each side of me slightly forward?
Yes, it would be uneven. It's not that this is always a problem, but I think it will be a problem in your situation. Here's why:
If you were just taking a photo of an individual person or even just two or three people, then a light off to the side would work well. But this is a large group and that extends the distance that needs to be covered... not just front to back, but also left to right.
Suppose the light is on your right side. The people on that side will be nearer to the flash. The people on the opposite side will be farther. Keep in mind that every time the distance increases by a ratio of 1.4, the amount of light delivered to that farther point is cut in half. The rate at which the light will "fall off" as the distance increases. You want to make sure that the distance from the flash to each subject is near enough that it falls within, say, 1/3rd of a stop... or at least a half stop. When it gets to a full stop of difference then it's going to be very noticeable that the lighting is uneven. It would almost be better to have just a single light in center and then "wrap" the group in an arc so that they're all approximately the same distance from the light source (but if you're seriously thinking of doing that, make sure the nearest to farther subject distance are falling comfortably inside the depth of field for the shot.
From what I'm gathering about the flash sync, I'm going to need to use somewhere between f/11 and f/16 if it's sunny? And maybe be able to stop down a bit if it's overcast?
Thanks again!
The "sunny 16" exposure says that on a day with full sun (and we're talking middle-of-the-day sun... not early morning or late evening sun) you can use the baseline exposure of f/16 and then set the shutter speed to be the inverse of your ISO. So at ISO 100 (because there's no reason to use a faster ISO in full sun) you'd set the shutter speed to 1/100th. But that's JUST the baseline. Remember the exposure triangle... you can set any "equivalent" exposure you want. The Sunny 16 rule also goes on to say that "light" overcast or "light" shade will reduce the light by about 1 stop... so open up 1 stop to compensate. Medium is 2 stops, and heavy is 3 stops.
So in full sun you could use the base of ISO 100, f/16 and 1/100th. Or you could use an "equivalent" exposure of ISO 100, f/11, and 1/200th. You could even use an equivalent exposure of ISO 100, f/8, and 1/400th. BUT... YOU'RE ALSO USING FILL FLASH. That creates a constraint on your settings because you can't use a shutter speed which exceeds the flash sync speed of the camera (which, as I read the specs on the 6D, is 1/180th sec.) The shutter is capable of fully opening in half that time and then fully closing in half that time. If your flash fires before the mechanical focal plane shutter opens completely then part of the sensor will be covered when the flash fires and you'll have an uneven shot. That's why cameras have flash "sync" speeds.
The flashes aren't the main source of light when you're outside... the sun is. The point of the flash is just to ease the shadows so they're gentle shadows. When doing that, I find that starting out with the flash power reduced by 1 stop is a good starting point. Depending on the time of day I might reduce it a tiny bit less or a tiny bit more (often between -2/3rds or -1-1/3rd). Check your shots... you want to see that the sun is still casting a shadow, but the strength of it is reduced... that way the bright side of a person's face and the dark side of a person's face isn't several stops apart. Ideally you get them within about 1/3rd of a stop.
If using E-TTL mode then you just have to set the Flash Exposure Compensation setting to -1 and then tweak it up or down just slightly to get the look you want (you should go experiment doing this with your flash now... not on the day of the event. Be very comfortable knowing how to dial the flash power up and down in E-TTL mode.)
If using manual mode, then you do a bit a math, but it's easy math.
The Guide number of the speedlight is 60 meters. That's the distance that the flash can be from a subject and still provide adequate illumination for an exposure when firing at FULL power AND also assuming you have an f/1.0 lens (which of course you do not have... but the point of the f/1.0 assumption is that it makes the math VERY easy.)
All you do is divide the guide number of the flash by the actual f-stop you'll be using. So let's suppose you're using f/11. You'd divide 60 meters by 11 to arrive at 5.45 meters. That's the distance at which your flash can provide proper illumination at FULL power when the camera is set to f/11. You'd convert meters into feet ... which works out to about 18'.
Before you freak out that your flash isn't powerful enough to reach 25', keep in mind that you actually want to fire at 1 stop less (for fill), which means if you multiply 18 by 1.4 you'd get 25' again. (that means a subject 25' away will get about half as much light as a subject 18' away. So since the flashes are set to properly illuminate a subject 18' away... and get half the light at 25', but you WANT about half the light, this works out to be just what you wanted anyway.
Also keep in mind you can vary the amount of light EITHER by controlling the power level of the flash OR by moving the flash closer or farther from the subjects.
A shutter speed of 1/180th and f/11 is for FULL sun (no overcast of any kind... not even very thin clouds) and will technically be just a fraction of a stop over-exposed.
If there is some light overcast you'll need to open up the shutter by a stop to compensate. But in so doing, your flash will now be stronger than you had planned (since the flash and f-stop were set to compete with full sun and you no longer have full sun), so you'd have to dial the power back 1 stop on the flash when you open the shutter by 1 stop.
When you use flash enough, the relationship between f-stop, distance, and power levels will start to become 2nd nature.