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EC is nothing more than a way of telling the camera (when in auto or semi-auto modes) that you want things a little brighter or darker than it thinks they should be. That's all
How does EC differ from adjusting ISO ?
From JoeW's description it's more related to manipulating the Dynamic Range capabilities.
Is it less noisy than ISO in particular situations ?
such as if at ISO 6400 and it's not quite enough, would upping EC be better than pushing ISO up ?
What TiredIron said is exactly on target.
You are adjusting the exposure to be different than what the camera suggests.
If you are shooting in any mode but manual, then the camera will adjust the shutter speed or aperture to comply with your selection of aperture or shutter speed.
Using EC tells teh camera to do something different - because you think the camera's decision won't be correct.
The noise in the image depend on the iso and sensor combination and the amount of light the sensor gets, so your EC can effect the noise but that is not your primary concern.