I really like the portrait of the woman with the colored hair!
A snoot tends to put out a small, concentrated pool of light. Can a reflector work as a hair light? Sometimes, yes, depending on what light is hitting it, and the angle and distance of the reflector to the person. A metallized silver reflector for example, can reflect a lot of light, and if it is angled and held in place correctly, it might make a good hair light, but if the main light doesn't hit the reflector well, it might not work very well. In lighting, everything, and I mean everything, interrelates with everything else, and there are no hard and fast rules, but there are generalities.
Basically this is the generality: snoots are not nearly as versatile as are honeycomb grids which are paired with diffusing material. If the hairlight comes in at a steep angle, it will be "hot" light, so the angles of 11,12,1,2,and 3 o'clcok make the hair light or rim light "hot". Less-steep incoming angles make a hair or rim light less hot, and more diffuse, more subtle. This is why a snoot is not the best tool for lighting hair.
The "best" hair lighting is subtle, and is close to the main light's character, not "hot", not "look, I used a hairlight!" This is where a 10 degree or 20 degree or 35 degree honeycomb grid with a diffuser over the grid, is fantastic. Or, you can use a strip box, or small umbrella, or even a ceiling bounce off a wall, as a subtlle, soft, diffused source of hair lighting. As you have already learned, the light shaping tools for "real" studio flash units, like the grid you now own, make life much easier than making do with speedlights and makeshift light shaping tools.
For hair lighting, I would really,really suggest a honeycomb grid set for the second light, and a barn door set for it, and at least two diffuser attachments for the grid. This will give you fantastic hair lighting, from close distances; this is what grids and diffusers and barndoors are expressly for. The barn door set can also prevent lens flare, and can be used with one door almost closed, the other door wide open, so you can light the backdrop a little tiny bit, yet still control the light that would otherwise flare the lens.
The biggest issue with a speedlight and a DIY snoot is how to get the light to be subtle. It CAN be done, but again, remember the way light becomes specular, and "hot" when the angle it hits is steep in relation to the lens axis. Look into drinking straw snoots for speedlights if you want a project. YES, there are some massively heavy and big C-stands. My Avengers have a base that is roughly 30 inches in a circle, about like a regular light stand, so maybe the borrowed one was extra-massive?