Good point traveler, sometimes I get tunnled into thinking my subject always has to be dead center....she's not perfectly center but close enough that I know thats what was on my mind.
This is startling because dead center seems to me to be a very weak place for most subjects. I tried thinking why this is and have come to this mushy set of conclusions. When something is in the center, there is this implication that all parts of it are equally interesting and therefore attention can slide off the dead center to look at the edges with equal interest. Yet in most cases, the interesting areas are not symmetrical, there are important areas and there are blahh areas - and the blahh areas strike the eye as dead space and allow the interest to drain away.(for example, in the case of a person looking at something, one generally leaves more space in the direction the subject is actually looking, rather than behind his/her head which is clearly of little interest - unlesss there is an axe about to enter it)
Secondly, few subjects are actually alone in the frame; the best pictures - even portraits- show a connection between the subject and something, even the viewer, and this connection is what creates interest in the picture - the dramatic tension, so to speak, that encourages the viewer to get involved and try to intuit what the connection is about. This is clearly what is happening in your picture - the connection between child and the woman who is dandling her in the pool is clearly the strongest part of the image- without this connection the image would have not much to interest the viewer.
(For another example, this
link is to a picture I've posted showing someone looking out of the margin. Her gaze is intent on something and this obvious attention makes the picture more interesting - because she is tied to something. Note that it isn't important to know what that the connection is, so much as the existence of connection alone brings interest to the scene. I kept enough of the right side to make her not seem pressed up against the edge, yet she is clearly off-center.)
Re: burning in the face. IMO, yours is not a technically accurate picture with all the shades and tones and details. The burnt out highlights accurately give the impression of the situation in the bright light and reflections of a pool in the sun thus conveying the feelings of the situation more than some full-range
more-technically perfect image.