I bought a TC20e and tried it on my 300 2.8 and 70-200 and 200mm lenses...I returned it for a full refund after looking at two days' worth of test images. There's nothing like compromising the output of a 70-200 at every focal length setting to make you regret using a 2x converter on a great lens. Same with the 300 and 200 primes--the 2x converter's penalty was simply too much lost quality,and two f/stops' worth of light gathering.
Nikon's 1.4x TC14e or TC14e-II are optically identical, and much better choices. If you need a long lens, or a ling zoom lens, it's probably best to get them. Given the high cost of the TC20e, and the low cost of the Sigma, buying a dedicated lens makes much more sense to me.