Master 1:1 macro photography first. Get a good control over focusing, composing and lighting. I say that because macro photography beyond 1:1 gets really hard really fast.
Increasing magnification there are a few options depending on what you want:
1) Diopters/macro lens attachments/macro filters (same thing people just call them different things). These all work by reducing your focusing distances, both your minimum and maximum. As a result the lens might only be able to focus a few inches away at best. They give the most magnification gain when used on longer focal length lenses.
Raynox (eg their DCR 250) produce a very high quality series with varying powers up to some very high diopter ratings. Canon also produces the 500D and 250D (the 250 is the more powerful) and are again high quality options.
Avoid cheap filters - you'll see them sold in packs with a group of them at a fairly low price - avoid! Most are very low grade single element optics that, whilst they work, will seriously degrade your image quality. (these are the ones most people encounter and earn them a very bad reputation)
2) Teleconverters - if the lens will physically mount to them you can use teleconverters to boost magnification. The gain is the same as the magnification ratio of the teleconverter, so on a 1:1 macro a 1.4TC would take you to 1.4:1 and a 2*TC would take you to 2:1.
Remember that teleconverters have a protruding front element and as such are physically restricted as to what lenses they can and cannot mount to. Kenko Pro series have the flattest front element protrusion whilst retaining high quality optics (go for the pro line only - avoid the cheaper Kenko line).
Personally I will often use a 1.4TC on a macro lens - I find that it gives a nice boost that helps resolve the segmented eyes on many flies, whilst at the same time having little impact on shooting difficulty and optical performance (esp when the lens is being shot at f13 and similar small apertures).
3) Extension tubes - work the same as diopters, but give more magnification (per unit of extension tube added) on shorter focal length lenses. I would generally say that at 100mm you're at the middle point for choosing between diopters and extension tubes; however if you want to go more extreme I would go for diopters. Adding anything more than the standard 65mm that comes in a complete set of Kenko extension tubes starts to get rather difficult to handle.
But first get a handle on 1:1 - then I'd suggest a 1.4TC if you can - 1.4:1 is a very nice working magnification. From there the sky is the limit - if you can get hold of things like the Raynox MSN 505 and the like which very high diopter ratings.